Physochemical Properties and Technology of Sodium m-Aminobenzene Sulfonate
Release time:
2023-11-30
Off-white to light red crystalline or slurry. Sodium m-aminobenzene sulfonate was obtained from nitrobenzene by sulfonation reaction and then reduced. Used in the manufacture of azo dyes and pharmaceutical intermediates, active, acidic, vulcanized and other dyes.
sodium m-aminobenzene sulfonate
Off-white to reddish crystal or paste. Sodium m-aminobenzene sulfonate was obtained from nitrobenzene by sulfonation reaction and then reduced. Used in the manufacture of azo dyes and pharmaceutical intermediates, active, acidic, vulcanized and other dyes.
physicochemical properties
White fine crystals, the decomposition temperature of the crystals obtained from water is 302~304 ℃.
Product quality
Appearance gray-white to light red crystal or paste
Total amino,% ≥ 60
Content,% ≥ 90
Insoluble matter content in soda ash,% ≤ 1.5
Use
Used in the manufacture of azo dyes and pharmaceutical intermediates, active, acidic, vulcanized and other dyes.
Production process route
The sulfonation reaction of nitrobenzene and fuming sulfuric acid was carried out at 115 ℃, the reaction product was neutralized to neutrality with liquid alkali, and filtered to obtain a sodium salt solution of m-nitrobenzene sulfonate. The solution is reduced with iron filings as catalyst to obtain sodium m-aminobenzene sulfonate, and the iron sludge is removed by filtration, and the filtrate is the sodium salt solution of m-aminobenzene sulfonate. Add sulfuric acid to the acidification pot until the Congo red test paper turns blue and keep the temperature at 70°C. Then the sodium m-aminobenzene sulfonate slurry was obtained by centrifugal filtration.
Toxicity and protection
This product is highly toxic. Swallowing or absorption through the skin can cause severe poisoning. However, its toxicity is much less than that of aniline and does not cause carcinogenesis. During the production process, it is necessary to prevent accidental clothing or splashing and skin, the production equipment should be sealed to prevent leakage, and the operators should wear protective equipment.
Packaging, storage and transportation
Use plastic bags, external use iron drum or wooden barrel packaging. 50kg per barrel. Store in a cool, ventilated and dry place, heat, moisture, sun protection. Storage and transportation shall be in accordance with the provisions of toxic substances.
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